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Charmander is only able to learn Metal Claw by leveling up in FireRed and LeafGreen, at level 13. In later generations, the move is only available to the Charmander line through breeding. It's likely that Charmander was given this move to ameliorate the comparative early disadvantage of picking the fire-type starter in Red and Green, when faced with the Pewter Gym and Mt. Moon, which contain many Pokémon strong against fire-type Pokémon.
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